LITHIUM THIOALKYNOLATES AND ITS REACTION WITH CARBONYL COMPOUNDS
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چکیده
منابع مشابه
the past hospitalization and its association with suicide attempts and ideation in patients with mdd and comparison with bmd (depressed type) group
چکیده ندارد.
The reaction of azide ions, N3, with metal carbonyl compounds; an electrospray mass spectrometry study
Monoand poly-nuclear metal carbonyls, and substituted analogues, have been analysed in the presence of N3 − ions by negative-ion electrospray mass spectrometry. Most complexes yield the appropriate isocyanate-containing anions by conversion of a CO ligand to an NCO one with elimination of N2. In some cases [M+N3] − ions are observed; for species such as H2Os3(CO)10 or Ru5C(CO)15 these arise fro...
متن کاملSynthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR].
The reaction between a transition metal carbonyl compound, L(n)MCO, and Li[Me(3)SiNR] yields the corresponding isocyanide derivative, L(n)MCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.
متن کاملCarbonyl Compounds Enols and Enolate Ons. Unsaturated and Polycarbonyl Compounds
ome of the most useful reactions of carbonyl compounds involve carbonhydrogen bonds adjacent to the carbonyl group. Such reactions, which can be regarded as the backbone of much synthetic organic chemistry, usually result in the replacement of the hydrogen by some other atom or group, as in the I I I I sequence H-C-C=O -+ X-C-C=O. The important examples we I I will consider in this chapter are ...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1979
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1979.535